By F. Albert, And Geoffrey Wilkinson, Cotton
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Additional resources for Advanced Inorganic Chemistry, Third Edition
Anal. Calc. 82. , and Lewis, W. (2014). Nucleophilic addition of TMSCCl3 to N-phosphinoyl benzaldimines: a route to N-phosphinoyl-α-(trichloromethyl)benzylamines. , 55, 5829–5831. 8 mmol), and the mixture was then stirred at room temperature for 1 h (monitored by 19 F NMR spectroscopy). Upon completion of the reaction, it was diluted with water and extracted with ethyl acetate. The combined organic extract was washed with brine, dried over sodium sulfate, and then concentrated in vacuo. The residue was purified by flash column chromatography on silica gel (petroleum ether/ EtOAc) to yield the desired product 3.
On completion of the reaction, the crude precipitated was filtered and washed with cold ethanol to obtain pure product of spirooxindole-pyrazoline 4. All the products were characterized by spectral studies. 6 (C ] O); MS: m/z (% rel) 331 (7), 329 (7), 317 (7), 315 (7), 258 (5), 256 (5), 224 (13), 170 (12), 168 (12), 91 (100), 65 (33). 2 (4 CH of Ar). MS: m/z (%rel) 410 (5), 368 (7), 341 (8), 279 (7), 236 (11), 213 (6), 173 (18), 149 (42), 127 (38), 105 (25), 97 (70), 83 (74), 69 (100), 57 (97).
X. (2012). Direct C-H arylation of quinones with anilines. Synlett, 23, 1621–1624. 5 mL) at room temperature. 6 mmol) in dichloromethane (2 mL) was added drop-wise with the help of a syringe. The resulting reaction mixture was then continued to stir at room temperature for 1-5 h and quenched with distillated water. The product was extracted with ether; solvent evaporated, and the crude product was purified using silica gel column chromatography to afford pure homoallyl alcohol 3 in good yield (66-97%).
Advanced Inorganic Chemistry, Third Edition by F. Albert, And Geoffrey Wilkinson, Cotton