By Robert C. West, Anthony F. Hill, Mark J. Fink

ISBN-10: 0123739780

ISBN-13: 9780123739780

Just about all branches of chemistry and fabric technology now interface with organometallic chemistry - the examine of compounds containing carbon-metal bonds. This generally acclaimed serial includes authoritative experiences that deal with all points of organometallic chemistry, a box which has increased drastically because the e-book of quantity 1 in 1964.* presents an authoritative, definitive assessment addressing all elements of organometallic chemistry* valuable to researchers inside this energetic box and is a needs to for each smooth library of chemistry* top of the range learn ebook inside this quickly constructing box

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The impetus for the wide and deep interest in this field is provided primarily by two fronts: the pressing need in the pharmaceutical industry to develop new drugs and the rapidly advancing scientific progress in establishing structure–function/structure–activity relationships and interrelationships of biologically active molecules. It is not too far from the truth to assert that together with C–C catenation, actually hand-in-hand with it, chirality of molecules defines the stuff of life. Because of the availability of a number of relatively simple methods to remove silyl groups from an organic compound to generate new derivatives, research in asymmetric hydrosilation has grown steadily in the last 15–20 years.

106 Functionalities on the ketone substrate such as halide, ether and tertiary amine are well tolerated and excellent conversions are achievable using a number of variations of 25 (pre-synthesized or generated in situ) with different N-substitution on the ring. Cl Cu N N 25 R1R2C=O + R3SiH 3 mol% (NHC) CuCl Toluene, 80°C NHC = N-Heterocyclic Carbene R1R2CH OSiR3 (19) 65-99% VII CATALYSIS BY ACIDS, BASES, OR FREE RADICALS The use of Lewis acids as catalysts for the hydrosilation of unsaturated compounds, hydrocarbons in particular, has seen a surge of interest and activity over the last dozen years.

A) The coupling of p-conjugation in polyacetylene (and related polyphenylenevinylenes) and s-conjugation in polysilanes to produce hybrid materials with potentially new or superior optical or optoelectronic properties, and/or to generate efficient ceramic precursors, has been an important area of research in silicon physics, chemistry and materials science. Interests have been driven by the advancing electronics industry and by new structural material needs, with a very broad range of potential applications.

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Advances in Organometallic Chemistry, Vol. 55 by Robert C. West, Anthony F. Hill, Mark J. Fink

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